Elizabeth Debicki turned heads at the New York premiere of The Man from U.N.C.L.E. on Monday.

The 25-year-old Australian actress walked the red carpet with co-stars Henry Cavill, Armie Hammer and Alicia Vikander at Ziegfeld Theatre. Debicki stunned in a cleavage-baring, pleated Valentino gown with gold print and simple metallic sandals.

The Man from U.N.C.L.E. is based on the NBC series of the same name, which ran from 1964 to 1968. The movie follows an American undercover agent (Cavill) who teams up with a Russian spy (Hammer) to stop a criminal organization during the Cold War.

The film is directed by Guy Ritchie, and opens in theaters Aug. 14. Debicki co-stars as the head of the criminal organization, with Hugh Grant as the head of U.N.C.L.E. and Alicia Vikander as the daughter of a missing German scientist.

Debicki is best known for portraying Jordan Baker in Baz Luhrmann's adaptation of The Great Gatsby. The actress will play Lady Macduff in Justin Kurzel's adaptation of Macbeth with Michael Fassbender, and is also scheduled for Everest with Jake Gyllenhaal.